Alabandite
A valid IMA mineral species - grandfathered
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About Alabandite
Formula:
MnS
Colour:
Iron black, brown, greyish black, green; dull brown (tarnished)
Lustre:
Sub-Metallic
Hardness:
3½ - 4
Specific Gravity:
3.95 - 4.04
Crystal System:
Isometric
Member of:
Name:
From the Spanish alabandina sulfúrea (sulfuric manganese) + the suffix, -ite, from the greek Λίθος (stone). The modern name alabandite come into use gradually. The term alabandine was first used by the French Mineralogist F. S. Beudant in 1832 in his Traite Elementaire de Mineralogie for a mineral first described earlier from Nagyág (today: Săcărâmb), Romania. The mineral was named as Schwarzerz by the local miners. Beudant derived this name (alabandine) from the Spanish alabandina sulfúrea (sulfuric manganese), a term used by del Rio (1804) for the same substance. del Rio used the term alabandina as a synonym of manganese in his binominal nomenclature (Papp 2004). It is not clear why del Rio used the term alabandicus for manganese, but Papp suggest that it may be related to the usage of both manganese minerals and lapis alabandicus in glass making.
The lapis alabandicus was a purplish black stone found near Alabanda, Asia Minor (near todays Araphisar, Turkey) mentioned by Pliny the elder (23-79) in his Naturalis Historia. Lapis alabandicus was known to be fusible and used in making glass. In some textbook it is suggested that the lapis alabandicus may be identical with the modern alabandite, but this is not confirmed.
The lapis alabandicus was a purplish black stone found near Alabanda, Asia Minor (near todays Araphisar, Turkey) mentioned by Pliny the elder (23-79) in his Naturalis Historia. Lapis alabandicus was known to be fusible and used in making glass. In some textbook it is suggested that the lapis alabandicus may be identical with the modern alabandite, but this is not confirmed.
Type Locality:
Polymorph of:
Galena Group.
At ambient pressure, alabandite (α-MnS) is the stable MnS polymorph from room temperature up to the melting point of 1655 °C (Staffansson, 1976; Kang, 2010).
At ambient pressure, alabandite (α-MnS) is the stable MnS polymorph from room temperature up to the melting point of 1655 °C (Staffansson, 1976; Kang, 2010).
Unique Identifiers
IMA Classification of Alabandite
Approved, 'Grandfathered' (first described prior to 1959)
Classification of Alabandite
2.CD.10
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
D : With Sn, Pb, Hg, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
D : With Sn, Pb, Hg, etc.
2.8.1.4
2 : SULFIDES
8 : AmXp, with m:p = 1:1
2 : SULFIDES
8 : AmXp, with m:p = 1:1
3.8.12
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
8 : Sulphides etc. of Cr, Mo, W an Mn
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
8 : Sulphides etc. of Cr, Mo, W an Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Abd | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Ala | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Alabandite
Sub-Metallic
Transparency:
Opaque
Colour:
Iron black, brown, greyish black, green; dull brown (tarnished)
Comment:
gray-white in polished section; deep green to brown and red in thin slivers.
Streak:
dark green, brown
Hardness:
3½ - 4 on Mohs scale
Hardness:
VHN100=164 - 176 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
on {100}
on {100}
Fracture:
Irregular/Uneven
Density:
3.95 - 4.04 g/cm3 (Measured) 4.053 g/cm3 (Calculated)
Optical Data of Alabandite
Type:
Isotropic
RI values:
n = 2.70
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Very High
Reflectivity:
Wavelength | R |
---|---|
400nm | 26.1% |
420nm | 25.9% |
440nm | 25.5% |
460nm | 24.8% |
480nm | 24.2% |
500nm | 23.7% |
520nm | 23.2% |
540nm | 22.9% |
560nm | 22.7% |
580nm | 22.5% |
600nm | 22.3% |
620nm | 22.1% |
640nm | 22.0% |
660nm | 21.9% |
680nm | 21.8% |
700nm | 21.8% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 26.1%.
Colour in reflected light:
Gray-white
Chemistry of Alabandite
Mindat Formula:
MnS
Elements listed:
Common Impurities:
Fe,Mg,Co
Crystallography of Alabandite
Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Fm3m
Setting:
Fm3m
Cell Parameters:
a = 5.2236 Å
Unit Cell V:
142.53 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals cubic or octahedral, to 1 cm. Commonly massive, granular.
Twinning:
Lamellar parallel to {111}
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0007513 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 1.8 | 293 | ||
0007514 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 3.01 | 293 | ||
0007515 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 3.25 | 293 | ||
0007516 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 3.57 | 293 | ||
0007517 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 5.81 | 293 | ||
0007518 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 7.19 | 293 | ||
0007519 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 8.56 | 293 | ||
0007520 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 7.85 | 293 | ||
0007521 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 11.3 | 293 | ||
0007522 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 11.8 | 293 | ||
0007523 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 12.3 | 293 | ||
0007524 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 13.8 | 293 | ||
0007525 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 17.1 | 293 | ||
0007526 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 20.1 | 293 | ||
0007527 | Alabandite | McCammon C A (1991) Static compression of alpha-MnS at 298 K to 21 GPa Physics and Chemistry of Minerals 17 636-641 | 1991 | 21.1 | 293 | ||
0018188 | Alabandite | Ott H (1926) Die Strukturen von Mn O, Mn S, Ag F, Ni S, Sn I4, Sr Cl2, Ba F2, Praezisionsmessungen einiger Alkalihalogenide. _cod_database_code 1011351 Zeitschrift fur Kristallographie 63 222-230 | 1926 | 0 | 293 | ||
0011353 | Alabandite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York rocksalt structure Crystal Structures 1 85-237 | 1963 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.015 Å | (14) |
2.612 Å | (100) |
1.847 Å | (50) |
1.509 Å | (20) |
1.306 Å | (8) |
1.1682 Å | (20) |
1.0662 Å | (16) |
Comments:
Synthetic (ICDD 6-518).
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 1: Primary nebular phases | 4.567-4.561 |
4 : Primary chondrule phases | 4.566–4.561 |
Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
5 : Primary asteroid phases | 4.566–4.560 |
Stage 3b: Earth’s earliest hydrosphere | >4.45 |
12 : Hadean hydrothermal subsurface sulfide deposits (see also #33) | |
High-𝑇 alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) | |
Stage 4b: Highly evolved igneous rocks | >3.0 |
36 : Carbonatites, kimberlites, and related igneous rocks | |
Stage 5: Initiation of plate tectonics | <3.5-2.5 |
38 : Ophiolites |
Geological Setting:
May occur in large quantities in epithermal polymetallic sulfide veins and especially in low-temperature manganese deposits. An uncommon constituent of a number of meteorites.
Type Occurrence of Alabandite
Synonyms of Alabandite
Other Language Names for Alabandite
German:Alabandin
Alabandit
Blumenbachit
Braunsteinblende
Braunsteinkies
Manganblende
Manganglanz
Schwarze Blende
Schwarzerz (in part)
Alabandit
Blumenbachit
Braunsteinblende
Braunsteinkies
Manganblende
Manganglanz
Schwarze Blende
Schwarzerz (in part)
Japanese:閃マンガン鉱
Russian:Алабандин
Simplified Chinese:硫锰矿
Spanish:Alabandita
Traditional Chinese:硫錳礦
Relationship of Alabandite to other Species
Member of:
Other Members of this group:
Altaite | PbTe | Iso. m3m (4/m 3 2/m) : Fm3m |
Clausthalite | PbSe | Iso. m3m (4/m 3 2/m) : Fm3m |
Galena | PbS | Iso. m3m (4/m 3 2/m) : Fm3m |
Niningerite | (Mg,Fe2+,Mn2+)S | Iso. m3m (4/m 3 2/m) : Fm3m |
Oldhamite | (Ca,Mg)S | Iso. m3m (4/m 3 2/m) : Fm3m |
Common Associates
Associated Minerals Based on Photo Data:
95 photos of Alabandite associated with Rhodochrosite | MnCO3 |
56 photos of Alabandite associated with Calcite | CaCO3 |
35 photos of Alabandite associated with Quartz | SiO2 |
16 photos of Alabandite associated with Pyrite | FeS2 |
11 photos of Alabandite associated with Tanzanite | {Ca2}{Al3}(Si2O7)(SiO4)O(OH) |
10 photos of Alabandite associated with Graphite | C |
9 photos of Alabandite associated with Sulphur | S8 |
9 photos of Alabandite associated with Manganese-bearing Calcite | (Ca,Mn)CO3 |
7 photos of Alabandite associated with Pectolite | NaCa2Si3O8(OH) |
7 photos of Alabandite associated with Rhodonite | CaMn3Mn[Si5O15] |
Related Minerals - Strunz-mindat Grouping
2.CD. | Svetlanaite | SnSe |
2.CD.05 | Herzenbergite | SnS |
2.CD.05 | Teallite | PbSnS2 |
2.CD.10 | Altaite | PbTe |
2.CD.10 | Clausthalite | PbSe |
2.CD.10 | Galena | PbS |
2.CD.10 | Niningerite | (Mg,Fe2+,Mn2+)S |
2.CD.10 | Oldhamite | (Ca,Mg)S |
2.CD.10 va | Quiroguite | Pb23Sb6S32 |
2.CD.10 | Keilite | (Fe2+,Mg)S |
2.CD.15a | Cinnabar | HgS |
2.CD.15b | Hypercinnabar | HgS |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Alabandite
mindat.org URL:
https://www.mindat.org/min-89.html
Please feel free to link to this page.
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External Links:
References for Alabandite
Reference List:
Klaproth, M. H. (1802) Chemische Untersuchung des Siebenbürgischen Schwarzerzes. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann, Berlin. p.35-43.
Hewett, D.F., Rove, O.N. (1930) Occurrence and relations of alabandite. Economic Geology: 25: 36-56.
Localities for Alabandite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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| Okoli, Benneth Ifenna, Agboola, Olufemi A., Onwualu, Azikiwe Peter, Bello, Abdulhakeem, Sholiyi, Olusegun Samuel, Anye, Vitalis C., Yusuf, Olatunbosun T. (2023) Characterization of Nigerian Zircon Sand and Its Suitability for Different Industrial Applications. Minerals, 13 (6) 711 doi:10.3390/min13060711 |
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| Balogh, K., Ahijado, A., Casillas, R., Fernández, C. (1999) Contributions to the chronology of the Basal Complex of Fuerteventura, Canary Islands. Journal of Volcanology and Geothermal Research, 90 (1). 81-101 doi:10.1016/s0377-0273(99)00008-6 Gutierrez, M., Casillas, R., Fernandez, C., Balogh, K., Ahijado, A., Castillo, C., Colmenero, J. R., Garcia-Navarro, E. (2006) The submarine volcanic succession of the basal complex of Fuerteventura, Canary Islands: A model of submarine growth and emergence of tectonic volcanic islands. Geological Society of America Bulletin, 118 (7). 785-804 doi:10.1130/b25821.1 |
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Uchucchacua Mine, Oyón District, Oyón Province, Lima, Peru